With the Champions League once again stealing all of the midweek attention, we have another stacked schedule from across the continent.
Alongside PSG’s blockbuster battle against Barcelona, there are nine Champions League showdowns pencilled in on Tuesday night.
For those of you looking to stick on a midweek flutter, we have taken a glance at some of Tuesday’s most attractive Champions League accumulator tips.
Tuesday, October 20th
BST 20:00 Liverpool vs Villarreal
Mounting a second-half comeback away at Brentford on Saturday as they eventually left west London with a gritty 2-1 victory, Liverpool appear to be relishing life under Andoni Iraola’s guidance.
While the Premier League giants might have marked their return from September’s international break with a downbeat 3-0 drumming at home against bitter domestic rivals Manchester City, it appears that was jus a minor blip for the Reds.
Getting their Champions League adventure underway with an eye-catching 2-1 win at home against Spanish heavyweights Atletico Madrid last month, the former Bournemouth boss has seen his squad muster back-to-back European victories.
With the mood in their camp at a real high, Liverpool have won four of their previous five appearances across all competitions and they will be confident of laying down another Champions League marker at Anfield.
Likewise, Iraola’s men also secured a 5-2 aggregate win when they last met Villarreal in the semi-final stage during the 2021/22 campaign.
Producing a sensational Champions League performance last week as they clinched a 3-1 victory against Italian icons Napoli, Villarreal should be excited by a trip to Anfield here.
However, showing some extended inconsistencies this season and scrapping it out in the bottom-half of the La Liga standings, Inigo Perez’s men will be bracing themselves for a monumental challenge.
Getting their Champions League adventure underway with a rollercoaster 3-2 loss at the hands of Borussia Dortmund on September 8th, Villarreal have also gained an unwanted reputation for their struggles on the road.
In fact, Tuesday’s guests have mustered just a sole win from any of their first six matchups away from the Estadio de la Ceramica across all competitions.
It should also be highlighted, the former Rayo Vallecano boss has not seen his squad claim a single clean sheet on their travels since back in February.
Betting Tip: Liverpool win @ 8/15 1xBet
20:00 Stuttgart vs Atletico Madrid
Putting a maiden Champions League victory on the board last week as they secured a 2-0 victory against Manchester United, Atletico Madrid have enjoyed quite the flurry on either side of September’s international break.
Last seen over the weekend snatching a dramatic late 1-0 win away at Espanyol, Diego Simeone’s men have come roaring back after their sluggish start to proceedings.
Heading into September’s extended international break with a stellar 2-1 win against arch-rivals Real Madrid, Tuesday’s guests are riding a serious wave of momentum.
In fact, Atletico have won each of their previous six consecutive appearances across all competitions and they will certainly be excited by a trip to Germany in midweek.
Currently sat in silver medal position among Spain’s elite, Simeone’s side have also shipped just a pair of strikes on their dominant six-match winning run and they do hold a real reputation for their defensive grit.
Crashing back down to earth over the weekend as they eventually fell to a toothless 1-0 loss at the hands of Bundesliga returners Hamburger, Stuttgart have shown some real inconsistencies since opening up the 2026/27 campaign.
Nevertheless, despite struggling to find much domestic stability since opening up the 2026/27 campaign, Die Roten have got their Champions League adventure underway with a real flurry.
Opening proceedings with a 3-1 victory against Norwegian outfit Viking on September 9th, Sebastian Hoeneb’s side have clinched consecutive European wins and they have their sights set on mounting a genuine knockout stage charge this year.
Despite facing a heavyweight challenge at the MHPArena on Tuesday night, that 1-0 defeat against Hamburger on Saturday afternoon is the only strike that Stuttgart have shipped in their previous three appearances across all competitions.
It’s also worth noting, Stuttgart have not seen any of their last four outings across all fronts finish with both teams finding the net.
Betting Tip: Both teams to score – No @ 13/8 BetUS
20:00 Porto vs PSG
Left heartbroken on foreign soil last week as they eventually slumped to a rollercoaster 3-2 defeat away at Spanish outfit Real Betis, Porto will know the importance of immediately dusting themselves down.
Nevertheless, getting their hands on a first domestic crown since 2022 last season, Tuesday’s hosts will certainly be excited to make a return to the Estadio do Dragao.
Marking their return from September’s extended international break with a 2-1 win against Maritimo, the Dragons once again hold a commanding five-point buffer at the top of the Primeira Liga standings.
Heading into September’s interval with a sensational 3-1 victory against arch-rivals Benfica, Porto will now be desperate to put a maiden Champions League victory on the board here.
Likewise, Francesco Farioli’s camp have suffered just a sole defeat in front of their own supporters so far this calendar year.
While PSV might have also enjoyed their own history-making domestic flurry last season, Tuesday’s guests have struggled to find a similar level this time around.
Putting in another concerning display over the weekend as they slumped to a 2-1 defeat at the hands of Den Haag, the Lightbulbs have now lost three of their previous four matchups across all fronts.
Heading into September’s international break with an action-packed 3-2 defeat against Twente, Peter Bosz’s side have also shown some glaring defensive struggles.
In fact, PSV have musterted just a sole clean sheet from any of their first 12 competitive appearances across all competitions so far this season and they are once again installed as a major underdog contender here.
It’s also worth noting, the reigning Dutch champions have lost their previous three straight matchups on their travels by an aggregate score of 6-3.
Betting Tip: Porto win & Both teams to score @ 21/10 1xBet
Our Tuesday’s Champions League Accumulator:
- Liverpool vs Villarreal – Liverpool win
- Stuttgart vs Atletico Madrid – Both teams to score – No
- Porto vs PSV – Porto win & Both teams to score
Place a £10 bet on our accumulator with BetUS and pocket £124.78 if all predictions are correct.
You can also visit our betting promotions section for the latest enhanced odds promos, accumulator bonuses and more.
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